For more than ten years, the US
Environmental Protection Agency (EPA) has been studying radon in
drinking water. Because of the cost of removing radon from water,
there has debate between the EPA and public water system operators
about what is an acceptable maximum contaminant level (MCL).
In 1988, the standard was expected to be
proposed at 10,000 picocuries per liter (pCi/L). In 1989, the expected
standard was dropped to 200 pCi/L. In the past year, proposals have
shifted to the 3,000 pCi/L range.
At this time, it appears that the EPA
will propose a radon standard for municipal drinking water in April
2000. This standard will drive the residential radon removal market.
The standard is now expected to be approximately 3000 pCi/L.
This moving target radon standard has
caused manufacturers to develop many different types of aeration
systems for radon removal.
Air stripping separates volatile
compounds from water. Compounds that air strip well evaporate easily
and are only slightly soluble in water. Gasoline components air strip
well because gasoline is very volatile and only a small amount
dissolves in water. Radon is so volatile that it is normally a gas and
it too is only slightly soluble in water. Radon is one of the most
easily air strippable compounds.
Air stripping is a transfer process.
The chemical contaminant is transferred from the water phase to an air
stream. The transfer of the contaminant takes place at the interface
between the water and the air.
Therefore, an increase in the amount
of liquid surface area in contact with the air stream will increase
the rate of volatilization of the radon into the air. The major design
variable for an air stripper is the production of large amounts of
air/water surface area.
Five basic types of air strippers are
available that can be used for radon removal. The goal of all these
systems is to generate as much air and water surface area as
efficiently as possible.
- Recirculating sprays. These systems
use the water pressure provided by the well pump to spray the
radon-laden water into a tank (see Figure 1). Air passing through the
tank contacts the small water droplets. The radon evaporates from the
surface of the water droplets and is carried out of the system with
the air stream.
The removal efficiency of a spray
nozzle system is usually in the range of 50 to 70 percent. To improve
this efficiency, a recirculation loop is sometimes added. This may
increase the efficiency to as much as 85 percent.
- Packed towers. Packed towers
generate air/water surface area by trickling the water through a bed
of packing material (see Figure 2). The packing material looks similar
to wiffle balls. As the water flows down through the bed of packing,
it coats the surface of the packing with a thin film of water.
A stream of air blown up through the
packing material contacts the water film and volatilizes the radon.
Typical efficiency of this type of residential system is approximately
92 percent.
- Venturi nozzles. A venturi nozzle
generates air/water surface area by forcing water through a nozzle at
high velocity (see Figure 3). The passage of the high velocity water
jet creates a suction and draws air into the water stream.
This is similar to what happens with a
fire hose where the force of the water jet draws in air from behind
the person holding the nozzle. A venturi nozzle can pull in about 1
cubic foot of air for every cubic foot of water that flows through the
nozzle. Radon removal efficiency using a single venturi nozzle is
about 70 percent.
- Diffused bubble aeration. Diffused
bubble systems are very simple in concept (see Figure 4). Bubble some
air up through a tank of water and the radon will transfer from the
water to the air. In practice it is a little more complicated than
that.
In this process, the mass transfer
area is limited to the surface area of the air bubbles. Therefore the
more air bubbled through the water and the smaller the bubbles are,
the more surface area will be generated.
Diffused bubble systems can have
efficiencies from 70 to 99.9 percent.
- Sieve trays. Sieve trays also bubble
air through water to generate surface area (see Figure 5). However,
they use a much larger volume of air to actually generate a froth of
air and water. This creates a very turbulent volatilization area that
generates very large amounts of mass transfer area. Sieve trays have
removal efficiencies of 99.9 percent.
GAC also plays a role
Another alternative radon removal
technology is granular activated carbon (GAC). Water treatment dealers
typically use GAC for taste and odor control and for chlorine removal.
Radon also adsorbs onto GAC.
However, because radon is a
radioactive element, it is constantly decaying and changing its form.
In a little over 3 days, half of the radon adsorbed on GAC will have
decayed to lead 210. Radioactive lead is a source of gamma radiation.
Gamma ray emission rates depend on the
radon concentration and the water treatment rate.
GAC should not be used for high radon
concentrations because of the possible gamma radiation problem that it
will generate. Some authorities recommend that GAC only be used on
radon concentrations less than 5,000 pCi/L. Gamma rays can be shielded
with lead or big tanks of water.
Size matters in air stripping
The installation procedures for most
aeration systems are quite similar.
Sizing the system is critical. This
requires an accurate measurement of the flow rate the well pump is
capable of producing. Use standard flow rate measurement techniques
recommended by the well pump manufacturers. If the well pump produces
too little water, it will starve the repressurization pump and cause
the system to shut down. .
Proper venting of the air stream from
the stripper is essential. The exhaust air can contain several
thousand picocuries per liter of radon in the air in some cases.
Air vent lines must be free of leaks,
and be vented at a location where the radon will not be drawn back
into the house. Typically the air vent should be located above the eve
line of the house and as far away from the doors and windows as
possible.
However, studies have shown that radon
in air levels dissipate to background levels within 5 to 6 feet of the
vent outlet. Be sure to follow the manufacturer's recommendation for
sizing the vent line. Undersizing this line will cause high-pressure
losses and significantly reduce the efficiency of any air strippers.
Interaction of the air stripper with
other water contaminants and water treatment systems must be
considered. Aeration of the groundwater will cause precipitation of
iron, manganese and hardness. Filters may need to be installed
following the air stripper. If other water treatment systems are
already installed, it is important to consider how the installation of
the air stripper may effect their operation. How the process train is
arranged will depend on the specific water quality at each location.
System maintenance is essential for
continued efficient operation. Regular testing of the radon removal
efficiency is necessary since radon is tasteless, odorless and
colorless. The homeowner has no other way to know whether the system
is operating correctly or not. A minimum of one test annually of the
untreated and treated water should be done. The system should also be
cleaned and disinfected annually. Any air filters should also be
checked, cleaned or replaced as needed annually.
Radon systems are generally sold
during real estate transactions. Therefore, the seller typically wants
to install the least expensive system possible. It is important that
the water treatment dealer sell a cost effective program that will
reliably meet the removal requirements and be easy to operate and
maintain.
If equipment is chosen carefully and
installed and operated correctly your customer can be satisfied with
an air stripping system. Proper design, selection, sizing,
installation and maintenance of air strippers provides a good answer
to a difficult water treatment problem.
Bruce L. Lamarre is chief technical
officer for North East Environmental Products, Inc., West Lebanon, NH.
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